X ray fluorescence spectroscopy
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This data contains high-resolution XRF data scanned from IODP cores recovered from Expedition 369, IODP Sites U1513, U1514 and U1516. Sietske Batenburg was responsible for scanning the Cenomanian-Turonian interval at Sites U1513 and U1516, and the lower half of the Eocene at U1514. Data is available from IODP database: http://web.iodp.tamu.edu/LORE/
This layer of the map based index (GeoIndex) shows the locations where stream sediment samples are collected under the G-BASE (Geochemical Baseline Survey of the Environment) programme at an average density of approximately one site per 1.5 km square. Analytical data for the minus 150 micron fraction of stream sediment samples are available for some or all of the following elements by a variety of analytical methods (now predominantly XRFS): Mg, P, K, Ca, Ti, Mn, Fe, V, Cr, Co, Ba, Ni, Cu, Zn, Ga, As, Se, Rb, Sr, Y, Zr, Nb, Mo, Pb, Bi, Th, U, Ag, Cd, Sn, Sb, Cs, La, Ce, Ge, Sc, Se, Br, Hf, Ta, W, Tl, Te and I. Stream sediment samples were also collected by the now defunct MRP programme and analytical data for the minus 150 micron fraction of samples is available for a variety of elements including Ag, As, Au, Ba, Bi, Ca, Ce, Cu, Fe, Mn, Mo, Ni, Pb, Sb, Sn, Sr, Ti, U, V, W, Zn and Zr. Some of the MRP samples may have undergone several stages of analysis, some for inclusion in the G-BASE project. The samples may have been assigned a different sample number but will plot at the same site. Data is available for most Great Britain, apart from some parts of Southern England which have yet to be surveyed.
This dataset was acquired as part of a NERC-funded Doctoral Training Partnership (DTP) PhD Studentship at the University of Leicester and British Geological Survey between 2014-2018 [grant no. NE/L002493/1] (see also Emmings, 2018 unpublished PhD thesis). This research was conducted within the Central England NERC Training Alliance (CENTA) consortium. This dataset accompanies a manuscript titled "Late Palaeozoic Phytoplankton Blackout: A 100 Myr Record of Enhanced Primary Productivity". Co-authors and co-workers were: Joseph F. Emmings (University of Leicester, British Geological Survey); Sarah J. Davies (University of Leicester); Simon W. Poulton (University of Leeds); Michael H. Stephenson (British Geological Survey); Gawen R. T. Jenkin (University of Leicester); Christopher H. Vane (British Geological Survey); Melanie J. Leng (British Geological Survey, University of Nottingham) and Vicky Moss-Hayes (British Geological Survey). Nick Riley (Carboniferous Ltd) is thanked for sharing biostratigraphic expertise and assistance. Nick Marsh and Tom Knott are thanked for providing assistance during geochemical analyses. This dataset contains the following data (in Microsoft Excel format). 1) Fe species abundance data measured at the University of Leeds using the sequential extraction method of Poulton and Canfield (2005) and pyrite S extraction method of Canfield et al., (1986); 2) Total Fe, Si, Mn and Al major element concentrations (measured using x-ray fluorescence at the University of Leicester; XRF); 3) Total organic carbon (TOC) and inorganic C (MINC) data measured via Rock-Eval pyrolysis at the British Geological Survey; 4) Cu, Mo and U trace element concentration data (measured via XRF at the University of Leicester) and enrichment factors relative to Post-Archaean Average Shale (PAAS; Taylor and McLennan, 1985). Analyses were coupled on 99 sample powders from three positions in the Craven Basin and spanning ammonoid biozones P2c-d to E1c1. See also http://dx.doi.org/10.5285/9ceadcad-a93c-4bab-8ca1-07b0de2c5ed0 for additional sedimentological and geochemical data from Hind Clough, MHD4 and Cominco S9. These data were also interpreted together with 20 drill-core samples previously acquired from Hind Clough (‘HC01’ prefix). See http://dx.doi.org/10.5285/c39a32b2-1a30-4426-8389-2fae21ec60ad for further information regarding this drill-core dataset. References: Emmings, J. 2018. Controls on UK Lower Namurian Shale Gas Prospectivity: Understanding the Spatial and Temporal Distribution of Organic Matter in Siliciclastic Mudstones. Unpublished PhD Thesis. University of Leicester. Poulton, S. W. & Canfield, D. E. 2005. Development of a sequential extraction procedure for iron: implications for iron partitioning in continentally derived particulates. Chemical Geology 214, 209-221, doi:http://dx.doi.org/10.1016/j.chemgeo.2004.09.003. Canfield D., Raiswell R., Westrich J., Reaves CM, Berner RA. 1986. The use of chromium reduction in the analysis of reduced inorganic sulfur in sediments and shales. Chemical Geology, 54(1): 149-155. Taylor S, McLennan S. 1985. The Continental Crust: Its Composition and Evolution. Blackwell Scientific: London.
Zr/Rb, Ca/Ti, Rb/K ratios against depth (0.112 m to 62.686 m) and age ( 366 to 150190 yrs). NERC grant, NE/D012996/1, abstract Lake Tana, in the highlands of northern Ethiopia, is the source of the Blue Nile, one of the world's great rivers. Surprisingly, very little is known about the age and history of this lake: one estimate from the 1930's is that it was formed 10,000 years ago by a lava dam. Similarly, little is known about the climatic history of the wider region that comprises the Blue Nile headwaters, despite the fact that the Nile has long been recognized as critical to the resources of ancient and modern Egypt. New geophysical and core data, obtained by us in October 2003 and September 2004 with NERC support, show that the lake may be at least 40,000 years old. Our new data also show that the lake dried out at around 16,000 years ago, and almost certainly at apparently regular intervals during the later stages of the last Ice Age. It is possible that the lake dried because of intense droughts lasting one or two hundred years, and that the droughts were caused by disruption of Africa's monsoon climate when iceberg-laden meltwater from North America flooded the North Atlantic - the Heinrich events. In this new PalaeoTana Project, we aim to test these hypotheses by drilling a sediment core, up to 100m in length, from the northern basin of Lake Tana, in about 10m water depth, and about 2km from shore. The core will be scanned at high resolution using X-ray fluorescence, X-ray and colour imagery, geophysical and magnetic core-scanning technology, without damaging the sedimentary components. The resulting datasets will identify past desiccation events, which will be investigated in detail and interpreted by comparison to sediments of the known drying-out event at 16,000 years ago. Dating the sediments by appropriate methods including luminescence, tephrochronology, and Argon-Argon dating will allow precise estimates of the timing and duration of the drought events. The relative timing of these events in comparison with abrupt climatic events in ocean cores (especially Heinrich events), and in other continental records, will allow inferences about the global- scale mechanisms of abrupt climate change. The data can also be used to test climate models, and thus to help judge the accuracy of model-predicted abrupt climate change in the future. A long core record of past climate and environment from this part of Africa would have major significance for understanding both regional environmental change, because of the influence of the Nile on NE Africa and the eastern Mediterranean, and global climate. It will contribute to understanding how future changes in ocean temperature and circulation will affect global climate, especially in the heavily populated monsoon regions of Africa and Asia. It will also have significance for understanding the later stages of human evolution in and dispersal out of Africa, by providing a record of the environmental changes that influenced early human populations and their water, plant and hunting resources.
This data was generated at the University of Kiel, Germany by Wolfgang Kuhnt, paid for by Dr Littler as part of her 2016 NERC Moratorium Award. The data comprises XRF-derived elemental abundances from two Holes (A and B) for International Ocean Discovery Program (IODP) Site U1448, spanning approximately the Pliocene period.
Profile soil analyses are available from a number of BGS programmes, notably the Mineral Reconnaissance Programme (MRP) and the Geochemical Baseline Survey of the Environment (G-BASE) programme. Sampling depth and range of analytes determined is very variable for the MRP. G-BASE samples are consistently from 35 - 50 cm though since 2003 it has become routine practice in the G-BASE project to collect a top soil and deeper profile sample from the same site but only analyses the top soil and store the profile soil. This also applies in urban areas. The G-BASE profile soils were generally sieved to 150 microns before analysis and determined by XRFS for some or all of: Mg, P, K, Ca, Ti, Mn, Fe, V, Cr, Co, Ba, Ni, Cu, Zn, Ga, As, Se, Rb, Sr, Y, Zr, Nb, Mo, Pb, Bi, Th, U, Ag, Cd, Sn, Sb, Cs, La, Ce, Ge, Sc, Se, Br, Hf, Ta, W, Tl, Te and I. MRP samples can include profile samples from greater than 1 meter collected using a power auger and also include till samples. The G-BASE samples are collected at a density of 1 sample per two square kilometres in rural areas and 4 samples every kilometre square in urban areas. MRP sampling was more site specific generally collecting soil samples along lines at spacing intervals generally 25 - 250 m.
This layer shows data collected mainly by the Geochemical Baseline Survey of the Environment (G-BASE) programme. Geochemical data are available for soil samples for the Humber-Trent and East Anglia atlas areas (see the Geochemical atlas areas layer). Samples for East Midlands and part of Southeast England have been collected and are currently either undergoing analysis or data conditioning. More than twenty urban areas have also been sampled and top soil analyses are available for these urban areas (Belfast, Cardiff, Corby, Coventry, Derby, Doncaster, Glasgow, Hull, Ipswich, Leicester, Lincoln, Manchester, Mansfield, Northampton, Nottingham, Peterborough, Scunthorpe, Sheffield, Swansea, Stoke, Telford, Wolverhampton and York). Regional samples are collected at an average density of one site per 2 square kilometres, urban sampling is at a density of 4 samples per square kilometre. Top soil samples are collected at a depth of 5 - 20cm. It is sieved through a 2mm mesh and milled to less than 150 microns. The data include analyses for some or all of the following elements by XRFS: Mg, P, K, Ca, Ti, Mn, Fe, V, Cr, Co, Ba, Ni, Cu, Zn, Ga, As, Se, Rb, Sr, Y, Zr, Nb, Mo, Pb, Bi, Th, U, Ag, Cd, Sn, Sb, Cs, La, Ce, Ge, Sc, Se, Br, Hf, Ta, W, Tl, Te and I. Loss on Ignition (LOI) and pH (in a slurry of 0.01 M CaCl2 ) is now routinely determined on 50% of regional and all urban samples.
This layer of the map based index (GeoIndex) shows the locations of over 12,500 rock samples from the land area of the United Kingdom gathered as part of the Mineral Reconnaissance Programme (MRP). The Mineral Reconnaissance Programme (MRP), funded by the DTI, carried out baseline mineral exploration in Great Britain between 1972 and 1997. The programme has been subsumed into the new BGS Minerals Programme, also funded by the DTI. The rock samples have been analysed for a variety of major and trace elements, mainly by XRF.
Geochemical analysis of volcanic samples from Aluto, Fentale, and Kone volcanoes, Ethiopia. Data are referenced in Iddon et al., 2018: Mixing and Crystal Scavenging in the Main Ethiopian Rift Revealed by Trace Element Systematics in Feldspars and Glasses; https://doi.org/10.1029/2018GC007836.
Geochemical data has been collected on samples from new exposures of the 1883 deposits, revealed by the 2018 tsunamigenic flank collapse of Anak Krakatau, which provides improved stratigraphic context. Whole-rock data taken by X-ray Florescence shows no systematic stratigraphic correlation. Chemical data for transects across, and spot points on, plagioclase phenocrysts, including some trace element data, all obtained using Electron Probe Microanalysis (EPMA), with Backscatter electron (BSE) images of crystals, obtained using Scanning Electron Microscope, reveal complex zoning profiles. However, chemical data for transects across pyroxene phenocrysts, obtained using EPMA, show this phenocryst phase is largely unzoned. The dataset also includes chemical data for spots on Fe/Ti oxides, included on the rims of pyroxene, and obtained using EPMA. Matrix glass chemistry, obtained via EPMA, shows that the early eruptive ash is more evolved than the pyroclastic material that follows, and that there is a slight overall trend to a more homogenous, less evolved melt composition. The 1883 eruption of Krakatau was a large, cardera-forming eruption that caused approximately 36,000 fatalities. It is also the only eruption of its size to have accompanying written accounts.