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Final Report for UKCCSRC Call 2 Project C2-189. Novel Reductive Rejuvenation approaches for degraded amine solvents from PCC in power plants.
The data forms the basis of the paper Novella et al (2020 (https://doi.org/10.1016/j.epsl.2019.115973) and full interpretation can be found there. Basalt glass chips were supplied by Bramley Murton (Southampton) and the sample contexts are detailed in https://doi.org/10.1093/petrology/43.11.1987. New trace element data is provided for the clean basaltic glasses (all reported in ppm). The Vanadium isotope composition (del51V) is also reported for these chips. Uncertainties in these analyses are provided as 2-sigma. Updated estimates of the ferric iron content of these chips also provided, based on recalibration of the data reported by Shorttle et al 2015 (https://doi.org/10.1016/j.epsl.2015.07.017).
We undertook U-Pb analysis - both high precision ID-TIMS and high spatial resolution LA-MC-ICP-MS – to determine the age of the Wensleydale Granite. This was done in order to resolve the ambiguity surrounding an earlier (1974) Rb/Sr age determination.
UKCCSRC Call 2 Project C2-189. The data, which was produced as a result of a UK CCSRC Call 2 funded project, consists of the GC-MS characterisation results for the products collected from the rejuvenation tests of degraded amine sorbents from carbon capture and related model degradation compounds. The examined amine-based sorbent samples included one heavily degraded industrial MEA solvent, one degraded solid-supported polyethyleneimine sample and 6 model MEA degradation compounds (N-(2-Hydroxyethyl)-ethylenediamine, glycylglycine, 2-Oxazolidinone, 1-(2-Hydroxyethyl)-2-imidazolidinone, 1-(2-Hydroxyethyl)-imidazole, N-Acetylethanolamine. Novel reductive approaches, which were investigated as a potential means for rejuvenating the degraded amine sorbents and where the samples for characterisation were produced, included catalytic hydrogenation, hydrous pyrolysis and hydropyrolysis with platinum, nickel and molybdenum as the catalysts used. The dataset also contains some preliminary CO2 absorption test results for a degraded MEA solvent before and after rejuvenation with hydrous pyrolysis using a continuous reactor. Full technical details of the research are contained in the final report submitted to UK CCSRC.
The dataset contains three subsets: 1) W isotope data for reference materials and geological samples, 2) Pb isotope data for reference materials and geological samples and 3) Mo isotope data for reference materials and geological samples. The data was collected over a period of about two years in two different laboratories (University of Manchester and University of Bristol) using multi-collector ICPMS techniques. A description of the methods used to obtain the W and Mo isotope data can be found in Willbold et al. (2011) and Willbold et al. (2016). The determination of the Pb isotope data is detailed in Freymuth et al. (2016). The data of reference materials (standard solutions and geological reference materials) is used to assess the reproducibility and accuracy of the mass spectrometric setup at the time and used as uncertainty estimate for the geological sample data. References: Freymuth, H., Elliott, T., van Soest, M., Skora, S., 2016. Tracing subducted black shales in the Lesser Antilles arc using molybdenum isotope ratios. Geology 44, 987-990. Willbold, M., Elliott, T., Moorbath, S., 2011. The tungsten isotopic composition of the Earth's mantle before the terminal bombardment. Nature 477, 195-198. Willbold, M., Hibbert, K., Lai, Y.-J., Freymuth, H., Hin, R.C., Coath, C., Vils, F., Elliott, T., 2016. High-Precision Mass-Dependent Molybdenum Isotope Variations in Magmatic Rocks Determined by Double-Spike MC-ICP-MS. Geostandards and Geoanalytical Research 40, 389-403.
Petrological and geochemical data of sulphides and samples from the Muratdere Cu-Au-Mo porphyry deposit, Turkey. Samples were taken from several boreholes from the Muratdere mine in Western Turkey, courtesy of Stratex International (now Oriole Resources). This data contains petrological photographs and trace element concentration of ore minerals. This data was collected as part of the TeaSe consortium NERC grant in order to determine the concentration and hosting of critical and precious metals in various types of ore deposits and barren rocks from different geological environments. This data was collected and interpreted by researchers at Cardiff University and is used in a paper, available at https://doi.org/10.5382/econgeo.4638.
Geochemical analyses of melt inclusions, host minerals, and glasses from the 2014-15 Holuhraun eruption, Iceland. Published in: Hartley ME, Bali E, Neave DA, Maclennan J, Halldorsson SA (2018) Melt inclusion constraints on petrogenesis of the 2014–2015 Holuhraun eruption, Iceland. Contrib Mineral Petrol 173:10. doi:10.1007/s00410-017-1435-0
Geochemical analysis of and Ar/Ar dating for volcanic samples from Aluto volcano, Ethiopia. Data are referenced in Hutchison et al., 2016c: The eruptive history and magmatic evolution of Aluto volcano: new insights into silicic peralkaline volcanism in the Ethiopian rift; https://doi.org/10.1016/j.jvolgeores.2016.09.010
Sample locations and geochemical data from the Aurora Ni-Cu-PGE magmatic sulphide deposit, Northern Bushveld Complex, South Africa. Samples were taken from two boreholes on the La Pucella farm, courtesy of Pan Palladium Limited. This data contains petrological photographs; scanning electron microscope element maps and identification of platinum group minerals and precious metal minerals; and trace element concentration of ore minerals. This data was collected as part of the TeaSe consortium NERC grant in order to determine the concentration and hosting of critical and precious metals in various types of ore deposits and barren rocks from different geological environments. This data was collected and interpreted by researchers at Cardiff University and is used in a paper, available at https://doi.org/10.1016/j.oregeorev.2019.02.008.
Geochemical data for the upper 300cm of giant piston core MD04-2832. Core MD04-2832 was collected from the middle basin of Loch Sunart a fjord on the west coast of Scotland from the research vessel Marion Dufresne on the 15th of June 2004. This data resource includes five data sheets: (1) Geochemical data, (2) Bulk radiocarbon, (3) ICP-MS, (4) FRUITS and (5) Age Model. 1. Geochemical data sheet includes Bulk elemental data (Organic Carbon, Nitrogen, C/N ratio, N/C ratio), Isotopic data (δ13C and ẟ15N), Biomarker data (Alkanes, Fatty Acids, GDGT's) and thermosgravimetric data (% labile, recalcitrant and refractory organic matter). 2. Bulk Radiocarbon data sheet includes bulk radiocarbon data for ten sediment samples presented as % modern, 14C Age (years BP), ẟ14C and Δ14C. 3. ICP-MS data sheet includes metal data associated with mining activities within the fjords catchment. Data includes Zinc (Zn), Lead (Pb), Copper (Cu), Barium (Ba), Aluminium (Al) and elemental ratios of these metal normalized with Al concentrations. 4. The FRUITS data sheet contains the outputs from the FRUITS Bayesian isotopic mixing model (Fernandes et al., 2014) used to constrain the source (terrestrial vs marine) of the organic carbon found at site MD04-2832. The model used bulk elemental ratios (N/C), Isotopic (δ13C and ẟ15N) and biomarker data (GDGT - BIT Index) to calculate the terrestrial and marine OC fraction from each downcore sample. 5. The Age Model datasheet contains the age model produced by the BACON software package (Blaauw and Christen, 2011). The age model was developed with a combination of shell/foraminifera radiocarbon dates and radiometric dating (210Pb and 137Cs). Further details on the data can be found in Smeaton, C., Cui, X., Bianchi, T.S., Cage, A.G., Howe J.A., Austin, W.E.N., (2021), The evolution of a coastal carbon store over the last millennium, Quaternary Science Reviews.