Major element analysis
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Major and trace elemental analysis of sulphide samples from the Beebe Vent Field. Geographical area - Beebe Vent Field, Cayman Trough, 18°32.798N,81°43.092W
This layer of the map based index (GeoIndex) shows the locations of over 12,500 rock samples from the land area of the United Kingdom gathered as part of the Mineral Reconnaissance Programme (MRP). The Mineral Reconnaissance Programme (MRP), funded by the DTI, carried out baseline mineral exploration in Great Britain between 1972 and 1997. The programme has been subsumed into the new BGS Minerals Programme, also funded by the DTI. The rock samples have been analysed for a variety of major and trace elements, mainly by XRF.
The data comprises a multi-proxy dataset of 49 samples spanning approximately the time interval from 1.8-3.9 Ma according to the currently available shipboard age model from offshore the Limpopo River, southwest Indian Ocean. Data includes major and trace element chemistry and K-Ar ages from the clay fraction (<2um), radiogenic isotope geochemistry, stable isotopes of planktonic foraminifera Globigerinoides ruber. The data set is now online with a citable DOI, although with an embargo till September 2019, http://dx.doi.org/10.1594/IEDA/100719
The dataset consists of a spreadsheet containing whole rock geochemistry (Major and trace elements, Hf isotopes) from 7 samples and zircon U-Pb, O, Hf isotope and trace elements compositions (>200 spots on zircons from 7 samples) analysed by Ion Microprobe (NERC EIMF) and MC-LA-ICP-MS (NIGL). The samples are Eoarchaean amphibolite-facies mafic gneisses and a pegmatite as well as granulite-facies mafic gneiss and migmatite (melano- and leucosome) from the Kapuskasing uplift in Ontario, Canada.
Major and trace element data for partial melts derived from high pressure-temperature experiments on a basaltic starting composition from the Ontong Java Oceanic Plateau.
Profile soil analyses are available from a number of BGS programmes, notably the Mineral Reconnaissance Programme (MRP) and the Geochemical Baseline Survey of the Environment (G-BASE) programme. Sampling depth and range of analytes determined is very variable for the MRP. G-BASE samples are consistently from 35 - 50 cm though since 2003 it has become routine practice in the G-BASE project to collect a top soil and deeper profile sample from the same site but only analyses the top soil and store the profile soil. This also applies in urban areas. The G-BASE profile soils were generally sieved to 150 microns before analysis and determined by XRFS for some or all of: Mg, P, K, Ca, Ti, Mn, Fe, V, Cr, Co, Ba, Ni, Cu, Zn, Ga, As, Se, Rb, Sr, Y, Zr, Nb, Mo, Pb, Bi, Th, U, Ag, Cd, Sn, Sb, Cs, La, Ce, Ge, Sc, Se, Br, Hf, Ta, W, Tl, Te and I. MRP samples can include profile samples from greater than 1 meter collected using a power auger and also include till samples. The G-BASE samples are collected at a density of 1 sample per two square kilometres in rural areas and 4 samples every kilometre square in urban areas. MRP sampling was more site specific generally collecting soil samples along lines at spacing intervals generally 25 - 250 m.
This dataset presents major (ICP-OES) and minor (ICP-MS) element data and fluid pH during interaction of simulated fracturing fluids with the Bowland-Hodder shale at a variety of conditions, i.e. fluid acidity (pH 1-5), temperature (25-70 C), and rock/fluid ratio (from 0.2:200 to 20:200), as well as two end member mineralogical compositions (from 618 m depth and 673 m depth). The data was collected under the SECURe (Subsurface Evaluation of CCS and Unconventional Risks funded under the European Union’s Horizon 2020 research and innovation programme under grant agreement number 764531. Data supplied by permission of University of Nottingham and British Geological Survey.
Primary data, model initial conditions, model results, a compiled database of olivine diffusivity experiments and supplementary tables used in the paper: 'Mutch, E. J. F., Maclennan J., Shorttle, O., Edmonds, M. & Rudge, J. F., (2019), Rapid trans-crustal magma movement under Iceland, Nature Geoscience'. Data_S1 contains electron probe microanalysis (EPMA) profile data of olivine crystals used in this study. This file also includes all of the initial conditions for forsterite content (XFo), Ni and Mn used in the diffusion modelling. Standard deviations are averaged values of standard deviations from counting statistics and repeat measurements of secondary standards. Data_S2 is a compiled database of olivine diffusion experiments used to derive multiple linear regressions for diffusion coefficients and associated covariance matrices. Regressions were only made through  data. Data_S3 contains median values for all of the inverted parameters estimated for each crystal profile from the Nested Sampling Bayesian inversion for each type of initial condition and model equation. All of the Monte Carlo realisations for each model are also included in this file. Table_S1 is a supplementary table that contains olivine diffusion equation regression parameters derived and used as part of this study. Table_S2 is a supplementary table that contains covariance matrices for olivine diffusion equations derived in this study. Table_S3 is a supplementary table that contains covariance matrices for aSiO2 (silica activity) dependent olivine diffusion equations derived in this study. Table_S4 is a supplementary table that contains angles between the EPMA profile and the main crystallographic axes in olivine as measured by EBSD. These angles are incorporated into the anisotropy calculation used to determine the apparent diffusivity parallel to the measured profile. angle100P, angle010P and angle001P are the angles between the profile and ,  and  respectively. Table_S5 is a supplementary table that contains ,median timescales and 1 sigma errors obtained from the posterior distributions of the Nested Sampling Bayesian inversion conducted on each olivine profile. The results using Al-based initial conditions, constant initial conditions (diffusion only), and aSiO2 based equations using Al-based initial conditions are presented here. The classification of each profile (growth-dominated vs. Al-decoupled) is also shown. See paper (Mutch, E. J. F., Maclennan J., Shorttle, O., Edmonds, M. & Rudge, J. F., (2019), Rapid trans-crustal magma movement under Iceland, Nature Geoscience) for more details.