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    Data derived from UKCCSRC Call 2 Project C2-181. The journal article can be found at http://dx.doi.org/10.1016/j.fuel.2017.03.072. Sorption enhanced chemical looping steam reforming of methane (SE-CLSR) relies on the exothermicity of both a metal catalyst’s oxidation and the in situ CO2 capture by carbonation onto a solid sorbent to provide the heat demand of hydrogen (H2) production by steam reforming while generating a nearly pure H2 product. A brief thermodynamic analysis to study the main features of the SE-CLSR process is done prior to the reactor modelling work. Later, one dimensional mathematical model of SE-CLSR process in the packed bed configuration is developed using gPROMS model builder 4.1.0 under the adiabatic conditions. This model combines reduction of the NiO catalyst with the steam reforming reactions, followed by the oxidation of the Ni-based reduced catalyst. The individual models of NiO reduction, steam reforming with in situ CO2 capture on Ca-sorbent, and Ni re-oxidation are developed by using kinetic data available in literature and validated against previous published work. The model of SE-CLSR is then applied to simulate 10 alternative cycles of the fuel and air feed in the reactor. The performance of the model is studied in terms of CH4 conversion, CO2 capture efficiency, purity and yield of H2. The sensitivity of the process is studied under the various operating conditions of temperature, pressure, molar steam to carbon ratio (S/C) and mass flux of the gas phase. In this work, the operating conditions used for the production of H2 represent realistic industrial production conditions. The sensitivity analysis demonstrates that the developed model of SE-CLSR process has the flexibility to simulate a wide range of operating conditions of temperature, pressure, S/C and mass flux of the gas phase.

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    The spreadsheet gathers the data collected during a brine:CO2 flow-through experiment conducted on a synthetic sandstone core sample to present the capabilities of a novel 'multiflow experimental rig for CO2 experiments' designed and assembled at the National Oceanography Centre, Southampton. The test was configured to assess geophysical monitoring techniques in shallow tight (North Sea-like) CO2 storage sandstone reservoirs. The tests were conducted in the rock physics laboratory at the National Oceanography Centre, Southampton, during 2015, as part of the DiSECCS project with funding from the United Kingdom's Engineering and Physical Sciences Research Council (EPSRC grant EP/K035878/1) and the Natural Environment Research Council (NERC). The experiment was a steady state brine-CO2 flow-through test to replicate CO2 geosequestration conditions and evaluate geophysical monitoring techniques. The confining and pore pressure conditions were similar to those estimated for shallow North Sea - like storage reservoirs, but simulating inflation/depletion cyclic scenarios for increasing brine:CO2 fractional flow rates. The data include ultrasonic P- and S-wave velocities and their respective attenuation factors, axial strains, and electrical resistivity; also relative permeability to both fluids (CO2 and brine) is displayed as a function of pore volume times, associated to increasing CO2 to brine contents in the sample.

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    The spreadsheet gathers the data collected during two experiments conducted on a synthetic sandstone core sample to assess geophysical monitoring techniques, storage capacity evaluation and the geomechanical integrity of shallow CO2 storage reservoirs. The tests were conducted in the rock physics laboratory at the National Oceanography Centre, Southampton, during 2016, as part of the DiSECCS project with funding from the United Kingdom's Engineering and Physical Sciences Research Council (EPSRC grant EP/K035878/1) and the Natural Environment Research Council (NERC). One experiment was a steady state brine-CO2 flow-through test (so called BTFT in the spreadsheet) to simultaneously evaluate storage capacity and identify pore fluid distribution and mechanical indicators during CO2 geosequestration. The confining and pore pressure conditions were similar to those estimated for shallow North Sea - like storage reservoirs, but simulating inflation/depletion cyclic scenarios for increasing brine:CO2 fractional flow rates. The second experiment focused on the assessment of geomechanical changes (the so called GAT in the spreadsheet) during and after CO2 storage activities under the same stress conditions. The data include ultrasonic P- and S-wave velocities and their respective attenuation factors and axial and radial strains in both tests, and electrical resistivity in the case of the flow-through test.

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    Compilation of CO2 release field experiments conducted worldwide for which the research results are publicly available prior to May 2017. This includes 14 field sites and 41 field experiments. For each field site, where possible, there is data on: The project: including primary aims, partners, total funding, duration, current status, website. Site information: including geology (target formation and overburden), hydrology, environment. Field experiment set-up: including injection depth, well orientation. Summary activity: total number of experiments at the site, total CO2 released. For each experiment at each site, where possible, there is data on: Injection parameters, including injection strategy, rate, duration, start and end date, CO2 source and properties, use of tracers; Site parameters, such as groundwater depth at time of experiment; Leakage to surface, including whether CO2 leakage to surface occurred, quantitation; Characteristics of surface leakage, including location, distribution, time taken to reach surface, evolution as experiment progresses; Subsurface CO2 spread, in soil gas and groundwater interaction, environmental impact; Monitoring including area monitored, duration of monitoring before, during, and after the release. Data sources are clearly cited.

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    Data derived from UKCCSRC Call 2 Project C2-181. The journal article can be found at https://doi.org/10.1016/j.ijhydene.2017.05.222. The sorption enhanced steam reforming (SE-SMR) of methane over the surface of 18 wt. % Ni/Al2O3 catalyst and using CaO as a CO2-sorbent is simulated for an adiabatic packed bed reactor. The developed model accounts for all the aspects of mass and energy transfer, in both gas and solid phase along the axial direction of the reactor. The process was studied under temperature and pressure conditions used in industrial SMR operations. The simulation results were compared with equilibrium calculations and modelling data from literature. A good agreement was obtained in terms of CH4 conversion, hydrogen yield (wt. % of CH4 feed), purity of H2 and CO2 capture under the different operation conditions such as temperature, pressure, steam to carbon ratio (S/C) and gas mass flux. A pressure of 30 bar, 923 K and S/C of 3 can result in CH4 conversion and H2 purity up to 65% and 85% respectively compared to 24% and 49% in the conventional process.

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    This Microsoft Excel document contains 5 worksheets providing data produced by research as part of UKCCSRC Call 1 funded project (grant number UKCCSRC-C1-31) and UKCCSRC funded international exchange. These data are presented and discussed in the manuscript "Geochemical tracers for monitoring offshore CO2 stores" by J. Roberts, S. Gilfillan, L. Stalker, M. Naylor, https://doi.org/10.1016/j.ijggc.2017.07.021. Then data details the assumptions around background concentrations of chemical tracers in the atmosphere and seawater, cost per litre, and how tracer detection concentrations (and so cost and potential environmental impact were calculated).

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    Dupont, Valerie (2017) Data associated with "Chemical equilibrium analysis of hydrogen production from shale gas using sorption enhanced chemical looping steam reforming" in Fuel Processing Technology. University of Leeds. Data file containing datasets used to generate the figures and tables in the paper. [Dataset] https://doi.org/10.5518/149. [Publication] http://doi.org/10.1016/j.fuproc.2017.01.026

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    This Microsoft Excel document contains 8 worksheets providing data produced by research as part of EPSRC Grant #EP/K036033/1. These data are presented and discussed in the manuscript "The Inherent Tracer Fingerprint of Captured CO2." by Flude, S. Györe, D., Stuart, F.M., Zurakowska, M., Boyce, A.J., Haszeldine, S., Chalaturnyk, R., and Gilfillan, S. M. V. (Currently under review at IJGGC). Data include samples collected, gas concentrations, stable isotope data and noble gas data. This data relates to publication https://doi.org/10.1016/j.ijggc.2017.08.010.

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    Fiscal metering could face several challenges during CO2 transport by pipelines due to the unusual physical properties of CO2 and CO2 mixtures. Coriolis flowmeters are an options to measure CO2 accurately in transport pipelines. However, the presence of impurities can affect the performance of the flowmeter. Therefore, the performance of a Coriolis flowmeter was evaluated using CO2 fluid with impurities in a mass flow-rig designed based on the gravimetric calibration in start / stop operations. In each test, the mass recorded by the Coriolis flowmeter was compared to the mass collected in the receiving facilities and measured using high accurate balance in order to obtain the relative deviation of the test. During the tests, in addition to the mass and volume flow rate, the operational pressure and temperature as well as velocity and density were recorded. The series of tests were conducted using different fluids, including: pure N2 (validation tests), pure CO2 (reference tests), pre-combustion mixture, post-combustion mixture, Oxyfuel-I mixture and Oxyfuel-II mixture. The recorded data as well as recorded and measured masses are available in the provided excel files for each investigated fluid. Grant number: UKCCSRC-C2-201

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    The spreadsheet gathers the data collected during an experiment conducted on a Utsira Sand formation core sample to complements and constrains existing geophysical monitoring surveys at Sleipner and, more generally, improves the understanding of shallow weakly-cemented sand reservoirs. The tests were conducted in the rock physics laboratory at the National Oceanography Centre, Southampton, during 2016, as part of the DiSECCS project with funding from the United Kingdom’s Engineering and Physical Sciences Research Council (EPSRC grant EP/K035878/1) and the Natural Environment Research Council (NERC). The experiment was a steady state brine-CO2 flow-through test to simultaneously evaluate ultrasonic waves, electrical resistivity (converted into pore fluid distribution) and mechanical indicators during CO2 geosequestration in shallow weakly-cemented reservoirs. The confining and pore pressure conditions were similar to those estimated for Sleipner (North Sea – like storage reservoirs), but simulating inflation/depletion cyclic scenarios for increasing brine:CO2 fractional flow rates. The data include primary ultrasonic wave velocities and attenuation factors, axial and radial strains, and electrical resistivity. Also, we provide a velocity-saturation relationship of practical importance to CO2 plume monitoring, obtained from the inversion of ultrasonic velocity and attenuation data and extrapolation of results to field-scale seismic-frequencies using a new rock physics theory. The dataset is linked to this publication: http://www.sciencedirect.com/science/article/pii/S1750583617306370.