Data accompanying: Emmings et al. A Mississippian Black Shale Record of Redox Oscillation. Palaeogeography, Palaeoclimatology, Palaeoecology [submitted July 2019] (NERC grant NE/L002493/1)

This is a geochemical dataset accompanying Emmings, J., Poulton, S., Vane, C., Davies, S., Jenkin, G., Stephenson, M., Leng, M., Lamb, A., Moss-Hayes, V. A Mississippian Black Shale Record of Redox Oscillation. Palaeogeography, Palaeoclimatology, Palaeoecology [submitted July 2019]. This dataset includes RockEval pyrolysis, major and trace element (XRF), Fe speciation, C, N and S isotopes and S species analyses through the Upper Bowland Shale in the Craven Basin (Lancashire, UK). This research was conducted by Joe Emmings, PhD researcher at the University of Leicester and British Geological Survey (BGS) between 2014-2018, and as a post-doctoral research associate (PDRA) at the British Geological Survey (2018-2021). The PhD research was funded by the Natural Environment Research Council (NERC), as part of the Central England Training Alliance (CENTA) [grant no. NE/L002493/1] and received CASE funding from the BGS. PDRA research was funded by the British Geological Survey. Reproduction or manipulation of these data in future analyses should cite one or more of the following related publications (as necessary): Emmings, J., 2018. Controls on UK Lower Namurian Shale Gas Prospectivity: Understanding the Spatial and Temporal Distribution of Organic Matter in Siliciclastic Mudstones. PhD Thesis, University of Leicester. Emmings J. et al. 2017. Stream and slope weathering effects on organic-rich mudstone geochemistry and implications for hydrocarbon source rock assessment: a Bowland Shale case study. Chemical Geology. 471. 74-91. Emmings, J. et al., 2019a. From Marine Bands to Hybrid Flows: Sedimentology of a Mississippian Black Shale. Sedimentology, [Accepted ms.]. Emmings, J.F. et al., 2019b. Controls on amorphous organic matter type and sulphurization in a Mississippian black shale. Review of Palaeobotany and Palynology, 268: 1-18. Emmings, J.F. et al. A Mississippian black shale record of redox oscillation. Palaeogeography, Palaeoclimatology, Palaeoecology [submitted July 2019] Co-workers: Sarah Davies (University of Leicester) - Primary PhD supervisor, sedimentology Chris Vane (BGS) - PhD supervisor, RockEval pyrolysis Mel Leng (BGS & University of Nottingham) - PhD supervisor, C & S isotopes Mike Stephenson (BGS) - PhD supervisor Simon Poulton (University of Leeds) - Fe speciation Gawen Jenkin (University of Leicester) - PhD supervisor Vicky Moss-Hayes (BGS) - RockEval pyrolysis Angela Lamb (BGS) - S isotopes

Date (Creation): 2019-09-17

Citation identifier: http://data.bgs.ac.uk/id/dataHolding/13607522

Point of contact

Organisation name	Individual name	Electronic mail address	Role
University of Leicester	Professor Sarah Davies	not available	Principal investigator
British Geological Survey	Enquiries	enquiries@bgs.ac.uk	Distributor
British Geological Survey	Enquiries	enquiries@bgs.ac.uk	Point of contact

Maintenance and update frequency: notApplicable

GEMET - INSPIRE themes, version 1.0

Geology

BGS Thesaurus of Geosciences

Isotopes
Sedimentary geology
Geochemistry
NGDC Deposited Data
Trace elements
Organic material
Palaeozoic

dataCentre

NGDC Deposited Data

Keywords

NERC_DDC

Access constraints: Other restrictions

Other constraints: no limitations

Other constraints: The dataset is made freely available for access, e.g. via the Internet. Either no third party data / information is contained in the dataset or BGS has secured written permission from the owner(s) of any third party data / information contained in the dataset to make the dataset freely accessible.

Use constraints: Other restrictions

Other constraints: The copyright of materials derived from the British Geological Survey's work is vested in the Natural Environment Research Council [NERC]. No part of this work may be reproduced or transmitted in any form or by any means, or stored in a retrieval system of any nature, without the prior permission of the copyright holder, via the BGS Intellectual Property Rights Manager. Use by customers of information provided by the BGS, is at the customer's own risk. In view of the disparate sources of information at BGS's disposal, including such material donated to BGS, that BGS accepts in good faith as being accurate, the Natural Environment Research Council (NERC) gives no warranty, expressed or implied, as to the quality or accuracy of the information supplied, or to the information's suitability for any use. NERC/BGS accepts no liability whatever in respect of loss, damage, injury or other occurence however caused.

Other constraints: Available under the Open Government Licence subject to the following acknowledgement accompanying the reproduced NERC materials "Contains NERC materials ©NERC [year]"

Language: English

Topic category

Geoscientific information

Geographic identifier: LANCASHIRE [id=154200]
British Geological Survey Gazetteer: Geographical hierarchy from Geosaurus 1979 creation

Begin date: 2014-09-30

End date: 2019-07-31

Unique resource identifier: OSGB 1936 / British National Grid (EPSG::27700)

Distribution format

Name	Version
MS Excel

Distributor contact

Organisation name	Individual name	Electronic mail address	Role
British Geological Survey	Enquiries	enquiries@bgs.ac.uk	Distributor

OnLine resource

Protocol	Linkage	Name
	https://www.bgs.ac.uk/services/ngdc/accessions/index.html#item130105	Data

Hierarchy level: Dataset

Other: dataset

Conformance result

Title: INSPIRE Implementing rules laying down technical arrangements for the interoperability and harmonisation of Geology

Date (Publication): 2011

Explanation: See the referenced specification

Pass: No

Conformance result

Title: Commission Regulation (EU) No 1089/2010 of 23 November 2010 implementing Directive 2007/2/EC of the European Parliament and of the Council as regards interoperability of spatial data sets and services

Date (Publication): 2010-12-08

Explanation: See http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2010:323:0011:0102:EN:PDF

Pass: No

Statement: Sedimentology - please see open-access publication Emmings, J. et al., 2019a. From Marine Bands to Hybrid Flows: Sedimentology of a Mississippian Black Shale. Sedimentology, [Accepted ms.] DOI: https://doi.org/10.1111/sed.12642. Total carbon and sulphur data were acquired using a LECO CS 230 elemental analyser at the University of Leicester. Major and trace element concentrations were measured on fused beads and powder briquettes with a PANalytical Axios Advanced X-Ray Fluorescence (XRF) spectrometer at the University of Leicester. Fe species data were measured at the University of Leeds via sequential extraction of 'highly reactive' Fe phases (method of Poulton and Canfield, 2005). Pyrite Fe content was estimated using the CrCl2 method of Canfield et al., 1986). Stable C and S isotopes were determined at the National Environmental Isotope Facility (NEIF)