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Mississippian Bowland Shale dataset: from Hind Clough, Marl Hill 4 (MHD4) and Cominco S9 (Craven Basin, UK). Iron Speciation, total organic carbon and selected major and trace element geochemical data (NERC grant NE/L002493/1)

This dataset was acquired as part of a NERC-funded Doctoral Training Partnership (DTP) PhD Studentship at the University of Leicester and British Geological Survey between 2014-2018 [grant no. NE/L002493/1] (see also Emmings, 2018 unpublished PhD thesis). This research was conducted within the Central England NERC Training Alliance (CENTA) consortium. This dataset accompanies a manuscript titled "Late Palaeozoic Phytoplankton Blackout: A 100 Myr Record of Enhanced Primary Productivity". Co-authors and co-workers were: Joseph F. Emmings (University of Leicester, British Geological Survey); Sarah J. Davies (University of Leicester); Simon W. Poulton (University of Leeds); Michael H. Stephenson (British Geological Survey); Gawen R. T. Jenkin (University of Leicester); Christopher H. Vane (British Geological Survey); Melanie J. Leng (British Geological Survey, University of Nottingham) and Vicky Moss-Hayes (British Geological Survey). Nick Riley (Carboniferous Ltd) is thanked for sharing biostratigraphic expertise and assistance. Nick Marsh and Tom Knott are thanked for providing assistance during geochemical analyses. This dataset contains the following data (in Microsoft Excel format). 1) Fe species abundance data measured at the University of Leeds using the sequential extraction method of Poulton and Canfield (2005) and pyrite S extraction method of Canfield et al., (1986); 2) Total Fe, Si, Mn and Al major element concentrations (measured using x-ray fluorescence at the University of Leicester; XRF); 3) Total organic carbon (TOC) and inorganic C (MINC) data measured via Rock-Eval pyrolysis at the British Geological Survey; 4) Cu, Mo and U trace element concentration data (measured via XRF at the University of Leicester) and enrichment factors relative to Post-Archaean Average Shale (PAAS; Taylor and McLennan, 1985). Analyses were coupled on 99 sample powders from three positions in the Craven Basin and spanning ammonoid biozones P2c-d to E1c1. See also http://dx.doi.org/10.5285/9ceadcad-a93c-4bab-8ca1-07b0de2c5ed0 for additional sedimentological and geochemical data from Hind Clough, MHD4 and Cominco S9. These data were also interpreted together with 20 drill-core samples previously acquired from Hind Clough (‘HC01’ prefix). See http://dx.doi.org/10.5285/c39a32b2-1a30-4426-8389-2fae21ec60ad for further information regarding this drill-core dataset. References: Emmings, J. 2018. Controls on UK Lower Namurian Shale Gas Prospectivity: Understanding the Spatial and Temporal Distribution of Organic Matter in Siliciclastic Mudstones. Unpublished PhD Thesis. University of Leicester. Poulton, S. W. & Canfield, D. E. 2005. Development of a sequential extraction procedure for iron: implications for iron partitioning in continentally derived particulates. Chemical Geology 214, 209-221, doi: http://dx.doi.org/10.1016/j.chemgeo.2004.09.003. Canfield D., Raiswell R., Westrich J., Reaves CM, Berner RA. 1986. The use of chromium reduction in the analysis of reduced inorganic sulfur in sediments and shales. Chemical Geology, 54(1): 149-155. Taylor S, McLennan S. 1985. The Continental Crust: Its Composition and Evolution. Blackwell Scientific: London.

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Identification info

Metadata Language
English (en)
Dataset Reference Date ()
2018-05-21
Identifier

http://data.bgs.ac.uk/id/dataHolding/13607326

 

British Geological Survey

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Enquiries


Environmental Science Centre, Nicker Hill, Keyworth

,

NOTTINGHAM

,

NOTTINGHAMSHIRE

,

NG12 5GG

,

United Kingdom

0115 936 3143
0115 936 3276
 

British Geological Survey

-

Enquiries


Environmental Science Centre, Nicker Hill, Keyworth

,

NOTTINGHAM

,

NOTTINGHAMSHIRE

,

NG12 5GG

,

United Kingdom

0115 936 3143
0115 936 3276
Maintenance and update frequency
notApplicable
GEMET - INSPIRE themes
  • Geology
BGS Thesaurus of Geosciences
  • TOC

  • Geochemistry

  • Trace elements

  • X ray fluorescence spectroscopy

Keywords
  • NERC_DDC

Limitations on Public Access
otherRestrictions
Other constraints
licenceOGL
Other constraints
Available under the Open Government Licence subject to the following acknowledgement accompanying the reproduced NERC materials "Contains NERC materials ©NERC [year]"
Use constraints
otherRestrictions
Other constraints

The copyright of materials derived from the British Geological Survey's work is vested in the Natural Environment Research Council [NERC]. No part of this work may be reproduced or transmitted in any form or by any means, or stored in a retrieval system of any nature, without the prior permission of the copyright holder, via the BGS Intellectual Property Rights Manager. Use by customers of information provided by the BGS, is at the customer's own risk. In view of the disparate sources of information at BGS's disposal, including such material donated to BGS, that BGS accepts in good faith as being accurate, the Natural Environment Research Council (NERC) gives no warranty, expressed or implied, as to the quality or accuracy of the information supplied, or to the information's suitability for any use. NERC/BGS accepts no liability whatever in respect of loss, damage, injury or other occurence however caused.

Other constraints

Available under the Open Government Licence subject to the following acknowledgement accompanying the reproduced NERC materials "Contains NERC materials ©NERC [year]"

Topic category
  • Geoscientific information
Extent

LANCASHIRE [id=154200]

Dataset Reference Date ()
1979

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Begin date
2015-07-13
End date
2017-03-24
Additional information

Three sections of the Bowland Shale Formation (Upper Bowland Shale) from the Craven Basin (Lancashire, UK). These sections are; outcrop Hind Clough (grid ref: 364430 453210, British National Grid projection), and boreholes Marl Hill 4 (MHD4; 367426 446752) and Cominco S9 (386010 463500). This study was funded by the Natural Environment Research Council (NERC), [grant no. NE/L002493/1], within the Central England NERC Training Alliance (CENTA). The study also received CASE funding from the British Geological Survey. Simon Poulton acknowledges support from a Royal Society Wolfson Research Merit Award. Nick Riley (Carboniferous Ltd) is thanked for sharing biostratigraphic expertise and assistance. Nick Marsh and Tom Knott are thanked for providing assistance during geochemical analyses.

 

Spatial Reference System

No information provided.

Distribution Information

Data format
  • MS Excel

    ()

Resource Locator
http://www.bgs.ac.uk/services/ngdc/citedData/catalogue/f4dacd24-795b-482c-877f-0e4fda6fe6da.html
Resource Locator
https://www.bgs.ac.uk/services/ngdc/accessions/index.html#item110292
Resource Locator
http://www.bgs.ac.uk/services/ngdc/citedData/catalogue/f4dacd24-795b-482c-877f-0e4fda6fe6da.html
Resource Locator
https://www.bgs.ac.uk/services/ngdc/accessions/index.html#item110292
 
Quality Scope
dataset
Other

dataset

Report

Dataset Reference Date ()
2011
Explanation

See the referenced specification

Degree

Report

Dataset Reference Date ()
2010-12-08
Explanation

See http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2010:323:0011:0102:EN:PDF

Degree
Statement

Samples were crushed and powdered using an agate planetary mill prior to analysis. Total sulphur was determined via LECO CS 230 elemental analysis. XRF data were acquired on fused beads and powder briquettes with a PANalytical Axios Advanced X-Ray Fluorescence spectrometer, default PANalytical SuperQ conditions. Pyrolysis was conducted on finely powdered samples in a Rock-Eval 6 apparatus. Fe speciation was conducted via sequential extraction of ‘highly reactive’ (FeHR), including carbonate-associated Fe (Fecarb), ferric (oxyhydr)oxides (Feox) and magnetite (Femag) (based on Poulton and Canfield, 2005). Pyrite Fe (FePY) was estimated via extraction of chromium-reducible S, which followed extraction of acid-volatile sulphide (based on Canfield et al., 1986). Trace element enrichment factors (EFs) are relative to Post-Archaean Average Shale values (from Taylor and McLennan, 1985).

Metadata

File identifier
6cf02f38-4bd2-36f9-e054-002128a47908 XML
Metadata Language
English (en)
Resource type
dataset
Metadata Date
2023-03-07
Metadata standard name
UK GEMINI
Metadata standard version

2.3

 

British Geological Survey


Environmental Science Centre,Keyworth

,

NOTTINGHAM

,

NOTTINGHAMSHIRE

,

NG12 5GG

,

United Kingdom

+44 115 936 3100
 
 

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