Mid-Ocean Ridge Basalt (MORB) Hafnium isotope data and eclogite trace element maps

Whole rock Hafnium (Hf) isotope data for mid-oceanic ridge basalt (MORB) samples from the Reykjanes ridge, Arctic Ocean, Equatorial MAR, South MAR, SEIR. The Hf isotope results are not yet published but will contribute to the mantle characterisation efforts detailed in Béguelin et al. (2025) ( https://doi.org/10.1029/2025GC012357). Mid-Ocean Ridge Basalt (MORB) glasses were crushed and sieved to ~600 µm. Chips were then hand-piked under a binocular microscope to remove alteration (only optically clear chips selected). Hf fractions were purified using the column chemistry protocol of Béguelin et al. (2017) and references therein ( https://doi.org/10.1016/j.gca.2017.09.015). Hf isotope ratios were measured on a Nu Instruments Plasma II mass spectrometer equipped with an Aridus desolvating nebuliser, on 50 ppb solutions. Accuracy and precision were monitored with repeated measurements of the JMC-475 standard (reported in dataset). Scanning Electron Microscopy-Energy Dispersive Spectrometry (SEM EDS) and Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry (LA-ICP-MS) major and trace elements maps of eclogites from the Raspas complex (Ecuador). Samples were prepared as 1-inch epoxy mounts. Samples are described in John et al. (2010) ( https://doi.org/10.1007/s00410-009-0427-0). The objective of this (present) work is to trace U, Pb and Th fluxes during subduction, as documented by obducted eclogites. Dataset includes SEM mapping of major elements with a Zeiss Sigma HD Field Emission Gun Analytical Scanning Electron Microscope (SEM) using energy dispersive X-ray spectroscopy (EDS). Elements measured are Fe, Ca, Cu, Ni, Mn, K, Na, Al, Mg, Ti, O, Cr, S, Si, P, Zr. Resolution is 25µm. Dataset also includes LA-ICP-MS mapping of trace elements using an Elemental Scientific ESL213 laser coupled to a Thermo Scientific iCap Q mass spectrometer. Elements measured are Rb, Sr, Mo, Cs, La, Yb, Pb, Th, U. Parameters: Raster spacing (resolution): 40µm, scan speed: 80 µm/s, rep rate: 20 Hz, fluence: 4.5 J/cm2, dwell time per element: 50 ms, injector: ESI dual concentric injector (DCI). SEM data are in weight %, LA-ICP-MS data are in µg/g (ppm). Data are unpublished, but further details can be found in the poster included with the dataset. Dataset was produced at the School of Earth and Environmental Sciences, Cardiff University, in the context of NERC grant NE/T012633/1 Mantle Circulation Constrained (MC2): A multidisciplinary 4D Earth framework for understanding mantle upwellings.

Date (Creation): 2025-10-15

Citation identifier: http://data.bgs.ac.uk/id/dataHolding/13608571

Point of contact

Organisation name	Individual name	Electronic mail address	Role
University of Bristol	Professor Tim Elliott	not available	Originator
University of Cardiff	Morten Andersen	not available	Originator
University of Cardiff	Paul Beguelin	not available	Originator
University of Bristol	Joey Rodney	not available	Originator
British Geological Survey	Enquiries	not available	Distributor
British Geological Survey	Enquiries	not available	Point of contact

Maintenance and update frequency: notApplicable

GEMET - INSPIRE themes, version 1.0

Geology

BGS Thesaurus of Geosciences

Citable Data
Eclogite
MORB
Hafnium isotopes
Major element analysis
Trace analysis
Isotopes
NGDC Deposited Data

dataCentre

Keywords

NERC_DDC

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Other constraints: licenceOGL

Other constraints: Available under the Open Government Licence subject to the following acknowledgement accompanying the reproduced NERC materials "Contains NERC materials ©NERC [year]"

Use constraints: Other restrictions

Other constraints: The copyright of materials derived from the British Geological Survey's work is vested in the Natural Environment Research Council [NERC]. No part of this work may be reproduced or transmitted in any form or by any means, or stored in a retrieval system of any nature, without the prior permission of the copyright holder, via the BGS Intellectual Property Rights Manager. Use by customers of information provided by the BGS, is at the customer's own risk. In view of the disparate sources of information at BGS's disposal, including such material donated to BGS, that BGS accepts in good faith as being accurate, the Natural Environment Research Council (NERC) gives no warranty, expressed or implied, as to the quality or accuracy of the information supplied, or to the information's suitability for any use. NERC/BGS accepts no liability whatever in respect of loss, damage, injury or other occurence however caused.

Other constraints: Available under the Open Government Licence subject to the following acknowledgement accompanying the reproduced NERC materials "Contains NERC materials ©NERC [year]"

Language: English

Topic category

Geoscientific information

Begin date: 2025-01-30

End date: 2025-04-04

Reference System Information

No information provided.

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Name	Version

Distributor contact

Organisation name	Individual name	Electronic mail address	Role
British Geological Survey	Enquiries	not available	Distributor

OnLine resource

Protocol	Linkage	Name
WWW:DOWNLOAD-1.0-http--download	https://webapps.bgs.ac.uk/services/ngdc/accessions/index.html#item190425	Data

OnLine resource

Protocol	Linkage	Name
WWW:LINK-1.0-http--related	https://doi.org/10.5285/a9cbce58-d20b-4881-a6bf-14ef7e777bcc	Citation Information - Digital Object Identifier (DOI)

Hierarchy level: Non geographic dataset

Other: non geographic dataset

Conformance result

Title: INSPIRE Implementing rules laying down technical arrangements for the interoperability and harmonisation of Geology

Date (Publication): 2011

Explanation: See the referenced specification

Pass: No

Conformance result

Title: Commission Regulation (EU) No 1089/2010 of 23 November 2010 implementing Directive 2007/2/EC of the European Parliament and of the Council as regards interoperability of spatial data sets and services

Date (Publication): 2010-12-08

Explanation: See http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2010:323:0011:0102:EN:PDF

Pass: No

Statement: Hf isotopes: MORB glasses were crushed, sieved and picked (~100 µm fragments) to avoid surface alteration. Samples were digested in HF and wash out of Mo chemistry were collected (Mo chemistry and subsequent work handled by Bristol collaborators). Hf was purified from resulting aliquots following the method of Béguelin et al. (2017, GCA 218). Hf isotopes were measured on a Nu plasma 2 mass spectrometer. Accuracy and precision were monitored by measurements of the JMC Hf standard and of the BHVO-2 and BIR-2 (values included in the dataset). SEC_SEM and SEC_laser files: SEM EDS and LA-ICP-MS major and trace elements maps of polished samples. SEM: 1 pixel = 25 µm. LA-ICP-MS: 1 pixel = 40 µm. Laser parameters: scan speed: 80 µm/s, rep rate: 20 Hz, fluence: 4.5 J/cm2, MS: Thermo iCap Q, dwell time per element: 50 ms, injector: ESI dual concentric injector (DCI).