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            <gco:CharacterString>Laser Ablation U-Pb analyses at the NERC Laboratories Keyworth. Polished blocks measuring 25 mm in diameter were made from a total of 6 samples covering the Los Chihuidos, Barda González, La Cuprosa, El Porvenir and Tordillos Cu deposits. These included a grain mount of calcite 3 from Los Chihuidos and 5 sediment blocks. These blocks were selected to cover all the localities and calcite generations available in the sample suite, The polished blocks were carbon coated and analysed using a Zeiss EVO SEM at the NHM, London. Each block was BSE montaged and sites of interest selected before SEM-CL imaging was conducted. The BSE analytical conditions were 20Kv acceleration voltage, 10 mm working distance and 1.5 nA probe current. For SEM-Cl imaging, the conditions were 20 kv acceleration voltage, 1 mm working distance from the CL detector and the probe current increased to 3 nA. Images were processed using Zeiss Digiscan II software. Following BSE and SEM-Cl imaging, each block was sliced to create a polished thick section and thin section. The thin sections were analysed using standard polarising microscope techniques to establish mineralogy and cement textures. Each thick section was BSE scanned using a Leo 1450VP SEM equipped with an Oxford Instruments X-Act 10mm2 detector at the National Oceanography Centre, Southampton prior to CL imaging. Analytical conditions were 20 kv acceleration voltage, 2 nA probe current and 19 mm working distance. Cl Imaging was conducted on a Lumin hot-stage Cl microscope at the NHM, London. The acceleration voltage used was 10 kv with a beam current kept at ~0.2 nA. Sites identified on the CL microscope were subsequently overlain onto the BSE scan for sample navigation. After fully imaging and characterising each thick section, the samples were sent to the BGS, Nottingham for in-situ U-Pb calcite geochronology. Laser ablation was performed using a New Wave Research 193UC excimer laser coupled to a Nu Instruments Attom single collector sector field mass spectrometer. A spot size of 50 µm was used. The full analytical setup for the laser and mass spectrometer are provided in Roberts and Walker (2016). Standard sample bracketing utilised the NIST614 glass standard (Jochum et al., 2011) to normalise the 207Pb/206Pb ratio (Pbc) whilst the calcite standard WC-1 (Roberts et al., 2017) was used to correct the 206Pb/238U ratio. Data uncertainty and propagation protocols follow Horstwood et al., (2016). The U-Pb heterogeneity of current carbonate mineral standards are often equal to or larger than the analytical uncertainties, meaning that significant excess variance will be present in the reference material U-Pb measurements (Roberts et al., 2017). If propagated into the sample point uncertainties as a within-session excess variance, as recommended for zircon in Horstwood et al., (2016), the data point uncertainties will be overestimated and will mask any small-scale real geological scatter in the sample and lead to ages with erroneously high precision. As per the recommendations of (Roberts et al., 2020), session-based reproducibility, accuracy and precision was performed on more homogeneous standards such as zircon or NIST glass standard. Accuracy of the method and secondary reference material is provided in thesis, doi:10.5258/SOTON/D3219, section 3.5.2. All results are plotted using a Tera-Wasserburg concordia diagram, taking the lower intercept as the age of the analysis. No common Pb correction was applied to the data.</gco:CharacterString>
          </gmd:statement>
        </gmd:LI_Lineage>
      </gmd:lineage>
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