1c7dd865-4fa0-2499-e054-002128a47908 English nonGeographicDataset non geographic dataset British Geological Survey +44 115 936 3100 Environmental Science Centre,Keyworth NOTTINGHAM NOTTINGHAMSHIRE NG12 5GG United Kingdom enquiries@bgs.ac.uk pointOfContact 2026-04-17 UK GEMINI 2.3 http://data.bgs.ac.uk/id/dataHolding/13606778 CO2GeoNet Paper: Carbonation of borehole seals: Comparing evidence from short-term laboratory experiments and long-term natural analogues 2013-03 publication http://data.bgs.ac.uk/id/dataHolding/13606778 It is crucial that the engineered seals of boreholes in the vicinity of a deep storage facility remain effective for considerable timescales if the long-term geological containment of stored CO2 is to be effective. These timescales extend beyond those achievable by laboratory experiments or industrial experience. Study of the carbonation of natural Ca silicate hydrate (CSH) phases provides a useful insight into the alteration processes and evolution of cement phases over long-timescales more comparable with those considered in performance assessments. Samples from two such natural analogues in Northern Ireland have been compared with samples from laboratory experiments on the carbonation of Portland cement. Samples showed similar carbonation reaction processes even though the natural and experimental samples underwent carbonation under very different conditions and timescales. These included conversion of the CSH phases to CaCO3 and SiO2, and the formation of a well-defined reaction front. In laboratory experiments the reaction front is associated with localised Ca migration, localised matrix porosity increase, and localised shrinkage of the cement matrix with concomitant cracking. Behind the reaction front is a zone of CaCO3 precipitation that partly seals porosity. A broader and more porous/permeable reaction zone was created in the laboratory experiments compared to the natural samples, and it is possible that short-term experiments might not fully replicate slower, longer-term processes. That the natural samples had only undergone limited carbonation, even though they had been exposed to atmospheric CO2 or dissolved View the MathML sourceHCO3- in groundwater for several thousands of years, may indicate that the limited amounts of carbonate mineral formation may have protected the CSH phases from further reaction. doi:10.1016/j.apgeochem.2012.09.007. http://www.sciencedirect.com/science/article/pii/S0883292712002594. Enquiries British Geological Survey 0115 936 3143 0115 936 3276 Environmental Science Centre, Nicker Hill, Keyworth NOTTINGHAM NOTTINGHAMSHIRE NG12 5GG United Kingdom enquiries@bgs.ac.uk author Enquiries British Geological Survey 0115 936 3143 0115 936 3276 Environmental Science Centre, Nicker Hill, Keyworth NOTTINGHAM NOTTINGHAMSHIRE NG12 5GG United Kingdom enquiries@bgs.ac.uk distributor Enquiries British Geological Survey 0115 936 3143 0115 936 3276 Environmental Science Centre, Nicker Hill, Keyworth NOTTINGHAM NOTTINGHAMSHIRE NG12 5GG United Kingdom enquiries@bgs.ac.uk pointOfContact notApplicable https://resources.bgs.ac.uk/images/geonetworkThumbs/1c7dd865-4fa0-2499-e054-002128a47908.png Geology GEMET - INSPIRE themes, version 1.0 2008-06-01 publication Carbon capture and storage BGS Thesaurus of Geosciences 2022 revision NGDC Deposited Data UKCCS dataCentre NERC_DDC otherRestrictions intellectualPropertyRights Either : (i) the dataset has not been formally approved by BGS for access and use by external clients under license; and / or (ii) the dataset contains 3rd party data or information obtained by BGS under terms and conditions that must be consulted before the dataset can be provided to, or accessed by, BGS staff or external clients. Refer to the BGS staff member responsible for the creation of the dataset if further advice is required. He / she should be familiar with the composition of the dataset, particularly with regard to 3rd party IPR contained in it, and any resultant access restrictions. This staff member should revert to the IPR Section (IPR@bgs.ac.uk) for advice, should the position not be clear. otherRestrictions The copyright of materials derived from the British Geological Survey's work is vested in the Natural Environment Research Council [NERC]. No part of this work may be reproduced or transmitted in any form or by any means, or stored in a retrieval system of any nature, without the prior permission of the copyright holder, via the BGS Intellectual Property Rights Manager. Use by customers of information provided by the BGS, is at the customer's own risk. In view of the disparate sources of information at BGS's disposal, including such material donated to BGS, that BGS accepts in good faith as being accurate, the Natural Environment Research Council (NERC) gives no warranty, expressed or implied, as to the quality or accuracy of the information supplied, or to the information's suitability for any use. NERC/BGS accepts no liability whatever in respect of loss, damage, injury or other occurence however caused. Either: (i) the dataset is made freely available, e.g. via the Internet, for a restricted category of use (e.g. educational use only); or (ii) the dataset has not been formally approved by BGS for access and use by external clients under licence, but its use may be permitted under alternative formal arrangements; or (iii) the dataset contains 3rd party data or information obtained by BGS under terms and conditions that must be consulted in order to determine the permitted usage of the dataset. Refer to the BGS staff member responsible for the creation of the dataset if further advice is required. He / she should be familiar with the composition of the dataset, particularly with regard to 3rd party IPR contained in it, and any resultant use restrictions. This staff member should revert to the IPR Section (ipr@bgs.ac.uk) for advice, should the position not be clear. English geoscientificInformation 2013-03 Enquiries British Geological Survey 0115 936 3143 0115 936 3276 Environmental Science Centre, Nicker Hill, Keyworth NOTTINGHAM NOTTINGHAMSHIRE NG12 5GG United Kingdom enquiries@bgs.ac.uk distributor https://www.sciencedirect.com/science/article/pii/S0883292712002594 WWW:LINK-1.0-http--link information https://ukccs-research.org/accessions/index.html#item77855 WWW:DOWNLOAD-1.0-http--download information nonGeographicDataset non geographic dataset INSPIRE Implementing rules laying down technical arrangements for the interoperability and harmonisation of Geology 2011 publication See the referenced specification false Commission Regulation (EU) No 1089/2010 of 23 November 2010 implementing Directive 2007/2/EC of the European Parliament and of the Council as regards interoperability of spatial data sets and services 2010-12-08 publication See http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2010:323:0011:0102:EN:PDF false CO2GeoNet was originally launched under the European Commission's 6th Framework Programme as a Network of Excellence (2004-2009) to promote research integration within the scientific community to help enable the implementation of CO2 geological storage. It was launched a non-profit scientific Association in 2008 registered under French Law so as to continue the networking accomplished under the European Commission's contract.