Analytical results from lightning discharge experiments focusing on interactions between nitrogen oxides and pyrite
The dataset includes measurements of dissolved and gaseous nitrogen oxides (nitrite, nitrate, NO(g)) generated by lightning discharge in a glass container partially filled with water, as well as measurements of dissolves sulfate and iron liberated from pyrite that has interacted with the nitrogen oxides. The lightning discharge experiments were carried out with either anoxic gas mixture (5% or 20% CO2 and the rest N2) or modern air. Lightning has long been identified as a source of reactive nitrogen species to Earth's early biosphere. These experiments were therefore conducted in order to test how this reactive nitrogen would interact with minerals at the Earth's surface. The results reveal that lightning-generated nitrogen oxides could have contributed to a small degree to oxidative weathering.
Simple
- Date (Creation)
- 2024-05-20
- Citation identifier
- http://data.bgs.ac.uk/id/dataHolding/13608240
- Point of contact
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Organisation name Individual name Electronic mail address Role University of St Andrews
Eva Elisabeth Stueeken
not available
Originator University of St Andrews
Annabel Long
not available
Originator University of St Andrews
Abu Baidya
not available
Originator British Geological Survey
Enquiries
not available
Distributor British Geological Survey
Enquiries
not available
Point of contact
- Maintenance and update frequency
- notApplicable
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GEMET - INSPIRE themes, version 1.0
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BGS Thesaurus of Geosciences
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Nitrogen oxides
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NGDC Deposited Data
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Archaean
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Lightning
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- dataCentre
- Keywords
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NERC_DDC
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- Access constraints
- Other restrictions
- Other constraints
- licenceOGL
- Use constraints
- Other restrictions
- Other constraints
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The copyright of materials derived from the British Geological Survey's work is vested in the Natural Environment Research Council [NERC]. No part of this work may be reproduced or transmitted in any form or by any means, or stored in a retrieval system of any nature, without the prior permission of the copyright holder, via the BGS Intellectual Property Rights Manager. Use by customers of information provided by the BGS, is at the customer's own risk. In view of the disparate sources of information at BGS's disposal, including such material donated to BGS, that BGS accepts in good faith as being accurate, the Natural Environment Research Council (NERC) gives no warranty, expressed or implied, as to the quality or accuracy of the information supplied, or to the information's suitability for any use. NERC/BGS accepts no liability whatever in respect of loss, damage, injury or other occurence however caused.
- Other constraints
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Available under the Open Government Licence subject to the following acknowledgement accompanying the reproduced NERC materials "Contains NERC materials ©NERC [year]"
- Language
- English
- Topic category
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- Geoscientific information
- Begin date
- 2022-08-01
- End date
- 2024-03-01
Reference System Information
- Distribution format
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Name Version MS Excel
- Distributor contact
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Organisation name Individual name Electronic mail address Role British Geological Survey
Enquiries
not available
Distributor
- OnLine resource
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Protocol Linkage Name https://webapps.bgs.ac.uk/services/ngdc/accessions/index.html#item184999 Data
- OnLine resource
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Protocol Linkage Name https://doi.org/10.5285/9d11f724-6abe-4b70-9471-dc298f8ff597 Digital Object Identifier (DOI)
- Hierarchy level
- Non geographic dataset
- Other
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non geographic dataset
Conformance result
- Date (Publication)
- 2011
- Explanation
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See the referenced specification
- Pass
- No
Conformance result
- Date (Publication)
- 2010-12-08
- Explanation
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See http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2010:323:0011:0102:EN:PDF
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- No
- Statement
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The experimental setup was similar to that of Barth et al. (2023, Nature Geoscience). Pyrite was added to the reaction flask, along with 21ml of deoxygenated DI-water. Nitrite, nitrate and nitric oxide gas, as well as sulfate and iron were measured over time by extracting 3ml of liquid every 6 minutes with a syringe through a septum. The analyses were conduced with an ion chromatograph for nitrite, nitrate and sulfate. Iron was measured by spectrophotometry. Nitric oxide gas was measured with an quadrupole mass spectrometer. Analytical details are described in Long et al. (in review). The aqueous data were corrected for the volume change that occurred as fluid was extracted. All experiments were carried out in triplicates. Blank experiments were conducted where the spark generator was turned off.
Metadata
- File identifier
- 190ccd7d-ccf4-2478-e063-0937940a7dff XML
- Metadata language
- English
- Hierarchy level
- Non geographic dataset
- Hierarchy level name
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non geographic dataset
- Date stamp
- 2024-09-07
- Metadata standard name
- UK GEMINI
- Metadata standard version
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2.3
- Metadata author
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Organisation name Individual name Electronic mail address Role British Geological Survey
Point of contact
- Dataset URI