UKCCSRC Call 1,2 paper: Understanding the solubility of water in carbon capture and storage mixtures: An FTIR spectroscopic study of H2O+CO2+N2 ternary mixtures
The solubility of water (H2O) in carbon dioxide (CO2) and nitrogen (N2) mixtures (xN2 = 0.050 and 0.100, mole fraction) has been investigated at 25 and 40 degrees C in the pressure range between 8 and 18 MPa. The motivation for this work is to aid the understanding of water solubility in complex CO2-based mixtures, which is required for the safety of anthropogenic CO2 transport via pipeline for carbon capture and storage (CCS) technology. The measurements have been performed using an FTIR spectroscopic approach and demonstrate that this method is a suitable technique to determine the concentration of water in both pure CO2 and CO2 + N2 mixtures. The presence of N2 lowers the mole concentration of water in CO2 by up to 42% for a given pressure in the studied conditions and this represents important data for the development of pipelines for CCS. This work also provides preliminary indications that the key parameters for the solubility of H2O in such CO2 + N2 mixtures are the temperature and the overall density of the fluid mixture and not solely the given pressure of the CCS mixture. This could have implications for understanding the parameters required to be monitored during the safer transportation of CO2 mixtures in CCS pipelines. The paper is available at http://www.sciencedirect.com/science/article/pii/S1750583615000444, DOI: 10.1016/j.ijggc.2015.02.002. UKCCSRC Grants UKCCSRC-C1-21 and UKCCSRC-C2-185.
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- 156d0854-1c57-2211-e054-002128a47908 XML
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- nonGeographicDataset
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- English (en)
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- Geoscientific information
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- GEMET - INSPIRE themes, version 1.0
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NGDC Deposited Data
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UKCCS
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Carbon capture and storage
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- 2015-04
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See the journal publication for details
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The copyright of materials derived from the British Geological Survey's work is vested in the Natural Environment Research Council [NERC]. No part of this work may be reproduced or transmitted in any form or by any means, or stored in a retrieval system of any nature, without the prior permission of the copyright holder, via the BGS Intellectual Property Rights Manager. Use by customers of information provided by the BGS, is at the customer's own risk. In view of the disparate sources of information at BGS's disposal, including such material donated to BGS, that BGS accepts in good faith as being accurate, the Natural Environment Research Council (NERC) gives no warranty, expressed or implied, as to the quality or accuracy of the information supplied, or to the information's suitability for any use. NERC/BGS accepts no liability whatever in respect of loss, damage, injury or other occurence however caused.
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There are no restrictions on the use that may be made of the dataset, although an appropriate copyright acknowledgement must be made when any part of the dataset is reproduced. Either no third party data / information is contained in the dataset or BGS has secured written permission from the owner of any third party data / information contained in the dataset to make the dataset freely available without any use constraints - inclusion of any third party data / information will affect the copyright acknowledgement that needs to be made.
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University of Nottingham
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University of Nottingham
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not available
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University of Nottingham
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not available
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University of Nottingham
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University of Nottingham
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not available
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University of Nottingham
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not available
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University of Nottingham
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not available
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University of Nottingham
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not available
Metadata information
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British Geological Survey
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enquiries@bgs.ac enquiries@bgs.ac.uk
- Metadata Date
- 2024-04-18
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- English (en)